Download PDF by G.R. Newkome: Advances in Dendritic Macromolecules. Volume 3

By G.R. Newkome

ISBN-10: 0762300698

ISBN-13: 9780762300693

The sequence Advances in Dendritic Macromolecules goals to hide the synthesis and supramolecular chemistry of dendritic or cascade super-molecules in addition to their much less excellent hyperbranched cousins.In quantity three, bankruptcy 1 describes the synthesis and characterization of dendrimers and hyperbranched polyesters, either according to 2,2-bis(hydroxymethyl)propionic acid, because the AB2-monomer. bankruptcy 2, discusses the benefits and downsides of dendritic molecular architectures essential to create polymeric natural magnetic fabrics. In bankruptcy three, Balzani and co-workers delineate their contributions to the sector of polynuclear transition steel complexes within the layout and development of dendritic nanostructures; those luminesence and redox-active complexes recommend their function as photochemical molecular units working via photoinduced power and electron move approaches. bankruptcy four, experiences the final growth on redox-active dendrimers, particularly as redox catalysts, natural conductors, transformed electrodes, and types for electron move proteins. bankruptcy five, summarizes the pioneering learn in organometallic dendritic macromolecules after which delineates the redox homes of a chain of silicon-based ferrocenyl-containing dendrimers.

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Extra info for Advances in Dendritic Macromolecules. Volume 3

Example text

The cross-linking gives, as expected, a dramatic increase in T for each system, but also reduces the differences in T^ as a function of the structure of the terminal groups. The height and width of the glass transition peak are changed, dependent on the terminal groups. This is indicative of a decreased mobility of the network containing hydroxyls, stronger polar interactions (relative to benzoate functional), and an even larger difference to the propionate functional structure. Since the amount of acrylic groups is the same for all resins, the decreased mobility can be attributed to the mobility of the terminal groups and not to the cross-linking density.

Science 1994,263, 1710. 22. Mourey, T. ; Turner, S. ; Fr^chet J. ; Hawker, C. ; Wooley, K. L. Macromolecules 1992,25,2401. 23. Flory, P. J. J. Am. Chem. Soc. 1952, 74,2718. 24. Chu, E; Hawker, C. J. Polym. Bull 1993,30, 265. 25. (a) Tlimer, S. ; Voit, B. ; Mourey, T. H. Macromolecules 1993, 26, 4617; (b) Turner, S. ; Walter, E; Voit, B. ; Mourey, T H. Macromolecules 1994,27,1611; (c) Kricheldorf, H. ; Stober, O. Macromol Rapid Commun. 1994,15, 87; (d) Wooley, K. ; Hawker, C. ; Fr^chet, J. M. J.

1992,114, 8405. 19. Newkome, G. ; Moorefield, C. ; Baker, G. R. Aldrichim. Acta 1992, 25, 31. 20. Tomalia, D. ; Naylor, A. ; Goddard III, W. A. Angew. Chem. Int. Ed. Engl 1990,29, 138. 21. Fr6chet, J. M. J. Science 1994,263, 1710. 22. Mourey, T. ; Turner, S. ; Fr^chet J. ; Hawker, C. ; Wooley, K. L. Macromolecules 1992,25,2401. 23. Flory, P. J. J. Am. Chem. Soc. 1952, 74,2718. 24. Chu, E; Hawker, C. J. Polym. Bull 1993,30, 265. 25. (a) Tlimer, S. ; Voit, B. ; Mourey, T. H. Macromolecules 1993, 26, 4617; (b) Turner, S.

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